(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline
(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline
CAS: 163169-29-7
Molecular Formula: C28H22FeNOP
(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline - Names and Identifiers
| Name | (S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline |
| Synonyms | (S,S)-ip-FOXAP (S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine (S)-1-(Diphenylphosphino)-2-[(S)-4-isopropyloxazolin-2-yl]ferrocene (2S)- 1-[(4S)-4,5-dihydro-4-(1-Methylethyl)-2-oxazolyl]-2-(diphenylphosphino)-Ferrocene |
| CAS | 163169-29-7 |
(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline - Physico-chemical Properties
| Molecular Formula | C28H22FeNOP |
| Molar Mass | 475.31 |
| Melting Point | 158-162℃ |
| Appearance | Crystalline Powder or Crystals |
| Color | Yellow to brown |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
| Sensitive | Air Sensitive |
(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline - Risk and Safety
| WGK Germany | 3 |
(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline - Introduction
(S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline, abbreviated as (S)-DIOP, is a chiral organic compound. Its chemical formula is C26H26FeNOP and its molecular weight is 465.3g/mol.
Nature:
(S)-DIOP is a red crystalline solid soluble in polar organic solvents such as methanol, dimethyl ether and tetrahydrofuran. It is stable in air, but insoluble in water. The compound can be characterized for its structure by X-ray crystallography.
Use:
(S)-DIOP is one of the important representatives of chiral ligands, which is widely used in asymmetric catalytic reactions. It can be used with transition metal catalysts for the synthesis of chiral organic compounds, such as drugs, pesticides and functional materials. It plays an important role in the synthesis of asymmetric hydrogenation, reduction, cyclization reaction of olefins with bisimides, and oxidation reaction.
Method:
The preparation of (S)-DIOP is generally accomplished in a two-step reaction. First, the metallocene precursor is synthesized by diphosphino; Then, it is reacted with 4-isopropyloxazoline to form (S)-DIOP. Care should be taken during the preparation to keep the reaction conditions dry and to avoid the presence of oxygen.
Safety Information:
(S)-DIOP has good safety, but because its toxicity and irritation have not been widely studied, it is still necessary to use and store the compound reasonably. During the operation, attention should be paid to protective measures to avoid direct contact with skin and inhalation. At the same time, it should be operated in a well-ventilated environment. For accidental contact or misuse, seek medical attention immediately.
Nature:
(S)-DIOP is a red crystalline solid soluble in polar organic solvents such as methanol, dimethyl ether and tetrahydrofuran. It is stable in air, but insoluble in water. The compound can be characterized for its structure by X-ray crystallography.
Use:
(S)-DIOP is one of the important representatives of chiral ligands, which is widely used in asymmetric catalytic reactions. It can be used with transition metal catalysts for the synthesis of chiral organic compounds, such as drugs, pesticides and functional materials. It plays an important role in the synthesis of asymmetric hydrogenation, reduction, cyclization reaction of olefins with bisimides, and oxidation reaction.
Method:
The preparation of (S)-DIOP is generally accomplished in a two-step reaction. First, the metallocene precursor is synthesized by diphosphino; Then, it is reacted with 4-isopropyloxazoline to form (S)-DIOP. Care should be taken during the preparation to keep the reaction conditions dry and to avoid the presence of oxygen.
Safety Information:
(S)-DIOP has good safety, but because its toxicity and irritation have not been widely studied, it is still necessary to use and store the compound reasonably. During the operation, attention should be paid to protective measures to avoid direct contact with skin and inhalation. At the same time, it should be operated in a well-ventilated environment. For accidental contact or misuse, seek medical attention immediately.
Last Update：2024-04-09 21:11:58
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Product Name: (S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline Request for quotationCAS: 163169-29-7
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Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Product Name: (S)[(Sp)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline Request for quotation
CAS: 163169-29-7
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Wechat: 17505222756
CAS: 163169-29-7
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Wechat: 17505222756
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